Yan Zhu, Cong Jiang, Heng Li, Ping Liu, Peipei Sun.Electrophotochemical Decarboxylative Azidation of Aliphatic Carboxylic Acids. Chiral Carbon Dots Derived from Serine with Well-Defined Structure and Enantioselective Catalytic Activity. Mengling Zhang, Wanru Zhang, Xing Fan, Yurong Ma, Hui Huang, Xiting Wang, Yang Liu, Haiping Lin, Youyong Li, He Tian, Mingwang Shao, Zhenhui Kang.Electrochemical Amidation: Benzoyl Hydrazine/Carbazate and Amine as Coupling Partners.

Tipu Alam, Amitava Rakshit, Hirendra Nath Dhara, Angshuman Palai, Bhisma K.

C–C Bond Activation of Cyclopropanes Enabled by Phosphine-Catalyzed In Situ Formation of High-Strain Methylenecycopropane Intermediate. Kui Liu, Gang Wang, Zhe-Wen Zhang, Yu-Yang Shi, Zhi-Shi Ye.The Journal of Organic Chemistry 2022, 87 Electrochemical Oxidative C–C Bond Cleavage of Ketones for C–N Bond Formation: A Route to Amides. Yonghui He, Liang Zeng, Ming Li, Lijun Gu, Shengyong Zhang, Ganpeng Li.Electrochemical Synthesis of Polysubstituted Sulfonated Pyrazoles via Cascade Intermolecular Condensation, Radical–Radical Cross Coupling Sulfonylation, and Pyrazole Annulation. Jiajun Feng, Yuzhi Wang, Luoyu Gao, Yang Yu, Jonathan B.The Journal of Organic Chemistry 2022, Article ASAP. One-Pot Synthesis of Diaryl 1,2-Diketones via Zn-Mediated Reductive Coupling. Zhi-Cheng Yu, You Zhou, Xiang-Long Chen, Jin-Tian Ma, Li-Sheng Wang, Yan-Dong Wu, An-Xin Wu.This article is cited by 123 publications. This review provides an overview on the most recent and significant developments in electrochemically oxidative selective C–C bond cleavage, with an emphasis on both synthetic outcomes and reaction mechanisms, and it showcases the innate advantages and exciting potentials of electrochemical synthesis. Encouragingly, more and more examples of the cleavage of C–C bonds via other maneuvers have recently been developed.

To date, the progress made in this area has mainly relied on Kolbe electrolysis and related processes. In this regard, electrochemical C–C bond cleavage has been identified as a sustainable and scalable strategy that employs electricity to replace byproduct-generating chemical reagents. However, the conventional chemical methods have largely involved the use of noble transition-metal catalysts as well as the stoichiometric and perhaps environmentally unfriendly oxidants, compromising the overall sustainable nature of C–C transformation chemistry. Selective C–C bond cleavage under mild conditions can serve as a valuable tool for organic syntheses and macromolecular degradation.

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